Further observations on the thermal stability of N-hydroxy-2-thiopyridone esters: Improved decarboxylative radical additions to olefins

Article abstract of DOI:10.1016/0040-4039(91)80854-Y

Decarboxylative radical addition onto olefins via thiohydroxamate esters can be considerably improved by heating and irradiating the reaction mixture; compound 10 can thus be obtained in 64% yield in one operation from acid chloride 6.