
Tetrahedron Letters p. 311 - 314 (1991)
Update date:2022-08-05
Topics:
Barton, Derek H. R.
Jaszberenyi, Joseph Cs.
Morrell, Andrew I.
Oxgen centered radicals, formed by the photolysis of derivatives of N-hydroxy-2-thiopyridone, have been trapped by vinyl ethers.In the case of the benzoyloxy radical, smooth deoxygenation is effected by IIIP compounds.Evidence for the formation of the dimethyltbutylsilyloxy and of the hydroxy radical is also presented.
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