Tetrahedron Letters p. 8035 - 8038 (1999)
Update date:2022-08-05
Topics:
Sulikowski, Gary A.
Lee, Sangku
An internal competition was used to estimate the kinetic isotope effect of an intramolecular metal carbene C-H insertion reaction alpha to a nitrogen atom. A stereoelectronic effect is proposed to explain the difference in magnitude of the observed KIEs for cis and trans diastereomers.
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