Equilibrium between homocub-1(9)-ene and homocub-9-ylidene

DOI: 10.1021/ja00013a038

Source and publish data:

Journal of the American Chemical Society p. 4981 - 4992 (1991)

Update date:2022-08-02

Topics:

Authors:

Chen, Ning

Jones Jr., Maitland

White, Walter R.

Platz, Matthew S.

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Article abstract of DOI:10.1021/ja00013a038

A combination of chemical trapping and laser flash photolysis experiments is used to demonstrate that homocub-9-ylidene and homocub-1(9)-ene are in equilibrium. The equilibrium constant can be shown to be close to unity at +20°C (0.23 ≤ K ≤ 4).

Full text of DOI:10.1021/ja00013a038

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