Stereoselective synthesis of E-β, β-disubstituted alkenylsilanes from α-(mesyloxy)allylsilanes

DOI: 10.1016/S0040-4039(00)92103-8

Source and publish data:

Tetrahedron Letters p. 855 - 856 (1991)

Update date:2022-09-26

Topics:

Authors:

Burke, Steven D.

Piscopio, Anthony D.

Kort, Michael E.

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Article abstract of DOI:10.1016/S0040-4039(00)92103-8

Cross-coupling reactions of various organocopper reagents with α-(mesyloxy)allylsilanes have been evaluated for stereoselective β,β-disubstituted vinylsilane synthesis. S_N2′ displacements with RMgBr/CuCN(cat.) reagents proceeded in high yields

Full text of DOI:10.1016/S0040-4039(00)92103-8

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