
Journal of the Chemical Society. Chemical communications p. 341 - 343 (1991)
Update date:2022-08-04
Topics:
Sekiguchi, Akira
Maruki, Ikutaro
Ebata, Keisuke
Kabuto, Chizuko
Sakurai, Hideki
7,7,8,8-Tetramethyl-7,8-disilabicyclo<2.2.2>octa-2,5-diene 1, prepared by the high-pressure reaction (10000 bar) of 1,1,2,2-tetramethyl-1,2-disilacyclohexa-3,5-diene and phenyl vinyl sulphoxide followed by elimination of benzenesulphenic acid, gave tetramethyldisilene (Me2Si=SiMe2) upon photolysis which underwent a photochemical <2 + 4> reaction with benzene at 10 K in an argon matrix to regenerate the precursor.
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