Journal of Organometallic Chemistry p. 273 - 286 (1991)
Update date:2022-08-04
Topics:
Lambert, Francois
Kirschleger, Bernard
Villieras, Jean
Stable organozinc compounds derived from alkyl-3-alkyl-2-(bromomethyl)-propenoates have been prepared.NMR 13C, 1H and IR studies show only one Z stereoisomer (no methylenic form) with a strong chelation between zinc and the carbonyl oxygen of the ester and solvated by only one solvent molecule.Hydrolysis can be achieved by two concurrent mechanisms with or without transposition.
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