Cycloaddition of Diphenylcyclopropenone with Carboximidate, Carboximidamide, and Carboximidothioate

DOI: 10.1246/bcsj.56.3849

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3849 - 3850 (1983)

Update date:2022-07-30

Topics:

Authors:

Yoshida, Hiroshi

Sogame, Shingo

Bando, Shoichi

Nakajima, Shosuke

Ogata, Tsuyoshi

Matsumoto, Kiyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.56.3849

The reaction of diphenylcyclopropenone with R¹N=C(R²)X (2) (R¹, R²=alkyl, aryl, X=MeO, EtO, MeS, or Me2N) gave 2-pyrrolin-4-one (3) in good yield.The less reactive carboximidothioate (2, R¹=4-MeC6H4, R²=Ph, X=MeS) yielded isomeric 3-pyrrolin-2-one together with 3.

Full text of DOI:10.1246/bcsj.56.3849

Products guided by the article

Product name:Benzenecarboximidothioic acid, N-(4-methylphenyl)-, methyl ester

Cas No:13432-42-3

R&D Labs maybe for 13432-42-3

Anhui Jiatiansen Agrochemical Co.,Ltd

Contact:15366811918

Address:chemical industrial park,xiangyu town,dongzhi county,anhui,china
Shaanxi Lighte Optoelectronics Material Co., Ltd.

Contact:+86-29-88320728-622/619/620

Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513

Relevant to this article

A Comparative Study of Solid State and Solution Aldol Addition Reactions of the Lithium Enolate of Methyl 3,3-Dimethylbutanoate: Stereochemistry and Mechanistic Implications

Doi:10.1016/S0040-4020(01)86317-1
(1993)
Activated phenacenes from phenylenes by nickel-catalyzed alkyne cycloadditions

Doi:10.1002/anie.201103428
(2011)
On the reactivity of imidazole carbamates and ureas and their use as esterification and amidation reagents

Doi:10.1016/j.tet.2011.09.057
(2011)
Synthesis of oligonucleotides carrying amino lipid groups at the 3′-end for RNA interference studies

Doi:10.1021/jo101143j
(2010)
Petasis olefination in a continuous-flow microwave reactor: Exo-glycals from sugar lactones

Doi:10.1055/s-0030-1261163
(2011)
Exploiting the ring strain in bicyclo[2.2.1]heptane systems for the stereoselective preparation of highly functionalized cyclopentene, dihydrofuran, pyrroline, and pyrrolidine scaffolds

Doi:10.1021/ol2027009
(2011)

Article Doi