Negative hyperconjugation does not play an important role in αfluoro sulfides: An experimental demonstration

DOI: 10.1016/0040-4039(91)80359-E

Source and publish data:

Tetrahedron Letters p. 1463 - 1466 (1991)

Update date:2022-09-26

Topics:

Authors:

Fujita, Makoto

Suzuki, Makoto

Ogata, Koreharu

Ogura, Katsuyuki

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Article abstract of DOI:10.1016/0040-4039(91)80359-E

Electrophilic oxidation of α-fluoro sulfides preferentially proceeded via and attack of the oxidant to the C-F bond. This result is inconsistent with the significant stereoelectronic effect based on the σ_C-F* n_S interaction (negative

Full text of DOI:10.1016/0040-4039(91)80359-E

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