Negative hyperconjugation does not play an important role in αfluoro sulfides: An experimental demonstration

DOI: 10.1016/0040-4039(91)80359-E

Source and publish data:

Tetrahedron Letters p. 1463 - 1466 (1991)

Update date:2022-09-26

Topics:

Authors:

Fujita, Makoto

Suzuki, Makoto

Ogata, Koreharu

Ogura, Katsuyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80359-E

Electrophilic oxidation of α-fluoro sulfides preferentially proceeded via and attack of the oxidant to the C-F bond. This result is inconsistent with the significant stereoelectronic effect based on the σ_C-F* n_S interaction (negative

Full text of DOI:10.1016/0040-4039(91)80359-E

Products guided by the article

Product name:((R)-(S)-1-Fluoro-propane-1-sulfinyl)-benzene

Cas No:134614-38-3

R&D Labs maybe for 134614-38-3

chemonlinephramacistdepot

Contact:86-607-68073220

Address:1 ave na road jiahua st
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd

Contact:0086-10-64430626

Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Xi'an Yuri Solar Co., Ltd

website:https://www.yurisolar.com/en

Contact:86--18092602675

Address:No. 560, East Hangtian Road, Xi'an, China
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA

Relevant to this article

Metabolic Inhibitors of O-GlcNAc Transferase That Act In Vivo Implicate Decreased O-GlcNAc Levels in Leptin-Mediated Nutrient Sensing

Doi:10.1002/anie.201803254
(2018)
Transition metal mediated asymmetric synthesis XII. Tricarbonyliron complexes as intermediates to isoquinuclidines

Doi:10.1016/0022-328X(91)86260-W
(1991)
An expeditious route to CoQ(n), Vitamins K₁ and K₂, and related allylated para-quinones utilizing Ni(0) catalysis

Doi:10.1016/S0040-4020(97)10222-8
(1998)
ELECTROCHEMICAL REDUCTION OF TRIORGANOHALO-SILANES AND -GERMANES

Doi:10.1016/S0022-328X(00)83697-9
(1980)
Synthesis and study of antimicrobial activities of variously chlorosubstituted 3-phenyloctahydropyrimido-[3,4-a]-s-triazines

Doi:10.1016/0223-5234(91)90215-9
(1991)
Palladium-catalysed cross-coupling reactions of arylboronic acids with π-deficient heteroaryl chlorides

Doi:10.1016/S0040-4020(01)80481-6
(1992)

Article Doi