2-Benzothiazolylchloromethyllithium: Synthesis of oxiranes

DOI: 10.1016/S0040-4039(00)74787-3

Source and publish data:

Tetrahedron Letters p. 7953 - 7956 (1992)

Update date:2022-08-05

Topics:

Authors:

Florio Florio

Troisi Troisi

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Article abstract of DOI:10.1016/S0040-4039(00)74787-3

Deprotonation of 2-chloromethylbenzothiazole 1 with lithium diisopropylamide (LDA) in tetrahydrofuran (THF) at -78°C gives a red solution of 2-benzothiazolylchloromethyllithium 2, which couples with carbonyl compounds furnishing oxiranes 3.

Full text of DOI:10.1016/S0040-4039(00)74787-3

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