Iodocyclization of the (Tolylsulfonyl)- and (Trichloroacetyl)carbamates of Secondary α-Allenic Alcohols. Highly Diastereoselective Synthesis of syn-1,2-Amino Alcohols and trans-5-Alkyl-1-oxo-2-oxazolidine-4-carboxylic Acids

DOI: 10.1021/jo00016a016

Source and publish data:

Journal of Organic Chemistry p. 4888 - 4895 (1991)

Update date:2022-08-02

Topics:

Authors:

Friesen, Richard W.

Kolaczewska, Aleksandra E.

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Article abstract of DOI:10.1021/jo00016a016

The iodocyclization of tosyl- and (trichloroacetyl)carbamates 9 and 10, respectively, of secondary α-allenic alcohols is described.The cyclofunctionalization reactions are highly diastereoselective, providing trans-5-alkyl-4-(1-iodoethylene)-2-oxazolidino

Full text of DOI:10.1021/jo00016a016

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