Stereoselective synthesis of naturally-occurring 7-(hetero)aryl (2E,4E,6E)-2,4,6-heptatrienamides and their structural analogues

Article abstract of DOI:10.1080/00397919108016755

A new and efficient highly stereoselective method to prepare naturally-occurring 7-(hetero)aryl (2E,4E,6E)-2,4,6-heptatrienamides and their structural analogues has been developed. The physical and spectral properties of one of these compounds, i.e. (2E,4E,6E)-7-(2-thienyl)-2,4,6-heptatrienoic acid piperidide (4b), have been found to be quite different from those previously reported for 7-(-2-thienyl)-2,4,6,-heptatrienoic acid piperidide isolated from Othantus maritimus to which the (2E,4E,6E)-configuration had been previously assigned.

Full text of DOI:10.1080/00397919108016755

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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Stereoselective Synthesis of
Naturally-Occurring 7-(Hetero)
Aryl (2E, 4E, 6E)-2, 4, 6-
Heptatrienamides and Their
Structural Analogues
Renzo Rossi a , Adriano Carpita a & Vito Lippolis a
a Dipartimento di Chimica e Chimica Industriale ,
Università di Pisa , Via Risorgimento 35, I-56126,
Pisa, Italy
Published online: 24 Sep 2006.
To cite this article: Renzo Rossi , Adriano Carpita & Vito Lippolis (1991)
Stereoselective Synthesis of Naturally-Occurring 7-(Hetero) Aryl (2E, 4E, 6E)-2, 4,
6-Heptatrienamides and Their Structural Analogues, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 21:3,
333-349, DOI: 10.1080/00397919108016755
To link to this article: http://dx.doi.org/10.1080/00397919108016755
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