A Selective Synthesis of (E)-Vinylsilanes by Cationic Rhodium Complex-Catalyzed Hydrosilylation of 1-Alkynes and Tandem Hydrosilylation/Isomerization Reaction of Propargylic Alcohols to β-Silyl Ketones

DOI: 10.1021/jo00115a020

Source and publish data:

Journal of Organic Chemistry p. 3045 - 3051 (1995)

Update date:2022-08-03

Topics:

Authors:

Takeuchi, Ryo

Nitta, Shuichi

Watanabe, Dai

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Article abstract of DOI:10.1021/jo00115a020

(E)-Vinylsilanes were obtained with high selectivities by BF4/2PPh3-catalyzed hydrosilylation of 1-alkynes with triethylsilane.A wide range of 1-alkynes were used.The hydrosilylation of propargylic alcohols with triethylsilane gave (E)-γ-silyl a

Full text of DOI:10.1021/jo00115a020

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