Catalytic Stereoselective Synthesis of α- or β-Glucosides Using a Single Glycosyl Donor, 1-O-2'-(2'-Methoxyethoxy)acetyl-Glucopyranose Derivative

Article abstract of DOI:10.1246/cl.1993.1373

In the presence of a catalytic amount of active acidic species generated from SnCl4 and AgClO4, various α-glucosides are stereoselectively synthesized in excellent yields from 1-O-2'-(2'-methoxyethoxy)acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose and alky