A NEW APPROACH FOR PREPARATION OF ATROPISOMERS OF ARYLPYRIDYLS VIA CROSS-COUPLING REACTIONS OF ARYL 2-(3-SUBSTITUTED)PYRIDYL SULFOXIDES WITH GRIGNARD AND ORGANOLITHIUM REAGENTS

DOI: 10.1016/0040-4039(91)80656-Q

Source and publish data:

Tetrahedron Letters p. 2943 - 2946 (1991)

Update date:2022-08-03

Topics:

Authors:

Shibutani, Tadao

Fujihara, Hisashi

Furukawa, Naomichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80656-Q

The cross-coupling reactions of phenyl 2-(3-substituted)pyridyl sulfoxides with 2-methoxyphenyl- and 1-(2-methoxy)naphthyl Grignard and 2-phenoxyphenyl lithium reagents afforded atropisomers of arylpyridyl derivatives in good yields which undergo thermal epimerization.

Full text of DOI:10.1016/0040-4039(91)80656-Q

Products guided by the article

Product name:1-(2-Benzenesulfinyl-pyridin-3-yl)-ethanol

Cas No:135276-67-4

R&D Labs maybe for 135276-67-4

MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang

Relevant to this article

Chemical modification of the multitarget neuroprotective compound fisetin

Doi:10.1021/jm2012563
(2012)
Enantioselective Synthesis of trans-Vicinal Diamines via Rhodium-Catalyzed [2+2] Cycloaddition of Allenamides

Doi:10.1002/adsc.201800021
(2018)
1,(ω-1)-Dienes: solvent controlled unilateral or bilateral metallation

Doi:10.1016/0022-328X(91)86133-B
(1991)
A concise asymmetric synthesis of (-)-rasfonin

Doi:10.1039/c1ob06700a
(2012)
Synthesis of some novel and complex thiopyrano indole derivatives from simple oxindole via intramolecular domino hetero Diels-Alder reactions

Doi:10.1016/j.tetlet.2011.10.133
(2012)
Phosphinoferrocene amidosulfonates: Synthesis, palladium complexes, and catalytic use in pd-catalyzed cyanation of aryl bromides in an aqueous reaction medium

Doi:10.1021/om2011529
(2012)

Article Doi