Tetrahedron p. 3829 - 3844 (1991)
Update date:2022-08-03
Topics:
Abad, Antonio
Arno, Manuel
Peiro, Miguel
Zaragoza, Ramon J.
A synthesis of (-)-auricularic acid (2a) starting from methyl (+)-13-oxo- podocarp-8(14)-en-19-oate (3a) and a synthesis of its C-4 epimer (2b) starting from methyl (+)-13-oxopodocarp-8(14)-en-18-oate (3b) are described. The absolute configuration of natural auricularic acid is stablished as (4R, 5S, 8S, 9R, 10S, 14S).
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Doi:10.1039/c1ob06385e
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