Total synthesis of milbemycins: A synthesis of (6R)-6-hydroxy-3,4- dihydromilbemycin E

DOI: 10.1039/b508670a

Source and publish data:

Organic and Biomolecular Chemistry p. 3636 - 3653 (2005)

Update date:2022-09-26

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Authors:

Helliwell, Madeleine

Karim, Sufia

Parmee, Emma R.

Thomas, Eric J.

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Article abstract of DOI:10.1039/b508670a

Following studies using benzyloxymethyl isopropenyl ketone 5 and ethyl 3-(3-furyl)-3-oxopropanoate 6, Robinson reactions between aryloxymethyl isopropenyl ketones 19 and 5 and ethyl 3-(2-trimethylsilyl-3-furyl)-3- oxopropanoate 20 were found to be stereos

Full text of DOI:10.1039/b508670a

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Product name:ethyl (1RS,2SR,3RS,5SR)-3-benzyloxy-2-hydroxy-5-methyl-2-(2-trimethylsilyl-3-furyl)-4-oxocyclohexane-1-carboxylate

Cas No:135352-16-8

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