Stereocontrolled preparation of tetrahydrofurans from acid-promoted rearrangements of allylic acetals

DOI: 10.1021/ja00014a030

Source and publish data:

Journal of the American Chemical Society p. 5354 - 5365 (1991)

Update date:2022-08-03

Topics:

Authors:

Hopkins, Mark H.

Overman, Larry E.

Rishton, Gilbert M.

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Article abstract of DOI:10.1021/ja00014a030

A new method for constructing substituted tetrahydrofurans from readily available allylic did and carbonyl components is reported (eq 1). This synthesis is highly stereocontrolled and allows carbon side chains to be incorporated at each carbon. Enantiomer

Full text of DOI:10.1021/ja00014a030

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