Tetrahedron Letters p. 3127 - 3130 (1991)
Update date:2022-08-04
Topics:
Lange, J. H. M.
Sommerdijk, N. A. J. M.
Dols, P. P. M. A.
Arnouts, E. G.
Klunder, A. J. H.
Zwanenburg, B.
Tricyclodecadienone epoxides 5 do not form an enolate on treatment with lithium diisopropyl amide, but instead undergo an unusual stereoselective β-hydride transfer leading to alcohols 6.The same type of epoxy endo-alcohol was obtained from parent epoxy ketone 5 on reaction with metal hydrides and organolithium reagents.These alcohols readily undergo an intramolecular epoxide migration by a Payne-type rearrangement, to give endo-epoxides 9.
View MoreZhejiang Tianyu Pharmaceutical Co., Ltd.
Contact:+86-576-84177669, 89189665,89189688,84168770
Address:Jiangkou Development Zone, Huangyan, Taizhou City, Zhejiang
Zhejiang Sanmei Chemical Industry Co., Ltd
Contact:86-579-87633213
Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Suqian Ruixing Chemical Co., Ltd.
Contact:+86-527-80805666（总机）;84836008(销售)
Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China
Contact:+86-21-38228826
Address:Room 505 Building 2, No 3377 Kangxin Highway, Shanghai, Republic China
Contact:0086 371 65711996
Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Doi:10.1021/ol203342e
(2012)Doi:10.1016/j.tetlet.2011.11.116
(2012)Doi:10.1002/chem.201304056
(2014)Doi:10.1007/s11164-011-0351-6
(2012)Doi:10.1016/j.dyepig.2016.05.010
(2016)Doi:10.1002/chem.201705373
(2018)
