Tetrahedron Letters p. 3127 - 3130 (1991)
Update date:2022-08-04
Topics:
Lange, J. H. M.
Sommerdijk, N. A. J. M.
Dols, P. P. M. A.
Arnouts, E. G.
Klunder, A. J. H.
Zwanenburg, B.
Tricyclodecadienone epoxides 5 do not form an enolate on treatment with lithium diisopropyl amide, but instead undergo an unusual stereoselective β-hydride transfer leading to alcohols 6.The same type of epoxy endo-alcohol was obtained from parent epoxy ketone 5 on reaction with metal hydrides and organolithium reagents.These alcohols readily undergo an intramolecular epoxide migration by a Payne-type rearrangement, to give endo-epoxides 9.
View Morewebsite:http://www.shengmaochem.com
Contact:86-27-82853423, 82819281
Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
Geen Chemical Technology Co., Ltd
Contact:86-769-21660847
Address:1408, Yingfeng Commercial Center, Nancheng District
Shanggao Ruiya Fine Chemicals Co., Ltd
Contact:+86-795-2592103
Address:Xingguang Nanlu,Shanggao County Industry Park
Contact:+86-371-55981030
Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.
Contact:15857995878 0579-82207761
Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Doi:10.1021/ol203342e
(2012)Doi:10.1016/j.tetlet.2011.11.116
(2012)Doi:10.1002/chem.201304056
(2014)Doi:10.1007/s11164-011-0351-6
(2012)Doi:10.1016/j.dyepig.2016.05.010
(2016)Doi:10.1002/chem.201705373
(2018)
