Journal of Organic Chemistry p. 4913 - 4918 (1991)
Update date:2022-08-04
Topics:
Marshall, James A.
Wang, Xiao-jun
Optically active (R)-(propargyloxy)acetic esters 5, available in ca. 90 percent ee through reduction of alkynones 2 with Chirald-LiAlH4 followed by alkylation with chloroacetic acid and esterification with CH2N2, undergo highly stereoselective <2,3> rearr
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