N-metallo imines: A new approach to α-amino alcohols from aldehydes

DOI: 10.1016/0040-4039(91)80664-R

Source and publish data:

Tetrahedron Letters p. 2967 - 2970 (1991)

Update date:2022-08-05

Topics:

Authors:

Cainelli

Giacomini

Mezzina Mezzina

Panunzio

Zarantonello

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80664-R

The addition of lithium alkyls or Grignard reagents to the in situ generated O-protected α-hydroxy-N-trimethylsilylimines proceeds in good yields and highly stereocontrolled manner to produce 1,2-aminols.

Full text of DOI:10.1016/0040-4039(91)80664-R

Products guided by the article

Product name:[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-eth-(E)-ylidene]-trimethylsilanyl-amine

Cas No:135560-62-2

R&D Labs maybe for 135560-62-2

Jinan Yufeng Bioengineering Co., Ltd.

Contact:+86-531-83130545/83130528/83130525/83130505

Address:Rm415,Building2,No19,Huaneng Road,Jinan, Shandong, China
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
LinHai Cina Chemical Co., LTD.

Contact:0576-85580989

Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
Anhui Charm Imp.&Exp.Co., Ltd

website:http://www.chinacharm.cn/

Contact:86 551 5316260

Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China
Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China

Relevant to this article

Palladium-catalyzed Suzuki-Miyaura cross-coupling reaction of potassium 2-pyridyl trifluoroborate with aryl (heteroaryl) halides

Doi:10.1016/j.tet.2011.12.036
(2012)
Aza-Diels - Alder reaction of methyl 2-[(R)-1-phenylethyl]iminoethanoate with cyclopentadiene using practical and environmentally friendly biphasic solvent system

Doi:10.1021/op049828m
(2005)
Preparation of new imidazol-2-yl-(amino)methylphosphonates, phosphinates and phosphine oxides and their unexpected cleavage under acidic conditions

Doi:10.1016/j.tet.2011.11.054
(2012)
Modification of N-terminal α-amino groups of peptides and proteins using ketenes

Doi:10.1021/ja208009r
(2012)
Chemo- and Regioselective Ring Construction Driven by Visible-Light Photoredox Catalysis: an Access to Fluoroalkylated Oxazolidines Featuring an All-Substituted Carbon Stereocenter

Doi:10.1002/adsc.201900585
(2019)
SYNTHESIS OF MACROLIDE ANTIBIOTICS. 22. SYNTHESIS OF THE C⁸-C¹³ FRAGMENT OF OLEANDONOLIDE

Doi:10.1007/BF00960425
(1991)

Article Doi