Halo(alkoxo) and Monocyclopentadienyl(halo)alkoxo Derivatives of Titanium, Zirconium and Hafnium

DOI: 10.1016/0022-328X(86)80453-3

Source and publish data:

Journal of Organometallic Chemistry p. 329 - 336 (1986)

Update date:2022-09-26

Topics:

Authors:

Gomez-Carrera, A.

Mena, M.

Royo, P.

Serrano, R.

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Article abstract of DOI:10.1016/0022-328X(86)80453-3

The chlorides MCl4 (M= Ti, Zr, Hf) react with the diols 4,4'-Me2C(C6H4OH)2 and 1,2-(OH)2Ar, Ar= C6H4, 4-MeC6H3, or 4-t-Bu-C6H3 to give the halogenoalkoxo derivatives MCl2(O2Ar).For M= Ti these react with bases L (L= 2,2'-bipy, THF, Et2O) to give the corre

Full text of DOI:10.1016/0022-328X(86)80453-3

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Product name:Cl^(1-)*Ti⁽⁴⁺⁾*C₅H₅^(1-)*(OC₆H₄)2C(CH₃)2^(2-) = ClTi(C₅H₅)(OC₆H₄)2C(CH₃)2

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