Halo(alkoxo) and Monocyclopentadienyl(halo)alkoxo Derivatives of Titanium, Zirconium and Hafnium

Article abstract of DOI:10.1016/0022-328X(86)80453-3

The chlorides MCl4 (M= Ti, Zr, Hf) react with the diols 4,4'-Me2C(C6H4OH)2 and 1,2-(OH)2Ar, Ar= C6H4, 4-MeC6H3, or 4-t-Bu-C6H3 to give the halogenoalkoxo derivatives MCl2(O2Ar).For M= Ti these react with bases L (L= 2,2'-bipy, THF, Et2O) to give the corre