A General Route to Enantiomerically Pure Sulfoxides from a Chiral Sulfite

DOI: 10.1021/jo00021a008

Source and publish data:

Journal of Organic Chemistry p. 5991 - 5999 (1991)

Update date:2022-07-29

Topics:

Authors:

Rebiere, F.

Samuel, O.

Ricard, L.

Kagan, H.B.

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Article abstract of DOI:10.1021/jo00021a008

Enantiomerically pure cyclic chiral sulfite (S)-7 (trans stereochemistry) has been easily obtained in two steps from (S)-ethyl lactate.This compound was found to react cleanly with many organometallics to give crystalline sulfinates with high regioselecti

Full text of DOI:10.1021/jo00021a008

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