Tetrahedron p. 5615 - 5624 (1991)
Update date:2022-07-29
Topics:
Clarke, Simon J.
Gilchrist, Thomas L.
Lemos, Americo
Roberts, Tony G.
Three hydrazones of ethyl bromopyruvate, the dinitrophenylhydrazone 2a, the toluene-4-sulphonylhydrazone 2b and the t-butoxycarbonylhydrazone 2c, have been reacted with a series of nucleophilic alkenes and heterocycles in the presence of sodium carbonate.Azoalkenes 3 are presumed as intermediates and adducts have been isolated.The azoalkenes derived from hydrazones 2a and 2c are found to be useful electrophiles and electrophilic dienes.Keywords: Azoalkenes; cycloaddition; ethyl bromopyruvate hydrazones; indoles; tetrahydropyridazines
View MoreShanghai doly chemical Co.,Ltd
Contact:+86-21-34716221
Address:No.328,WuHe Roard,MinHang,ShangHai China
Contact:+852-8198 2399
Address:9E, Leapont Industrial Building, 18-28 Wo Liu Hang Road, Shatin, New Territories, Hong Kong
Contact:+86-310-7092106
Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Hebei Fulong Import & Export Co., Ltd.
Contact:86-311-87795661
Address:15A19 Zhongyuan Building,368 Youyi North Street,Shijiazhuang 050070,China
Contact:+86-571-86217390
Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Doi:10.1016/j.bmcl.2012.04.021
(2012)Doi:10.1016/j.tet.2012.04.042
(2012)Doi:10.1016/j.bmc.2012.04.047
(2012)Doi:10.1039/c3gc40753e
(2013)Doi:10.1021/om300303a
(2012)Doi:10.1039/c2dt30548h
(2012)
