Angewandte Chemie - International Edition p. 1244 - 1247 (2012)
Update date:2022-08-04
Topics:
Ni, Zhikun
Zhang, Qian
Xiong, Tao
Zheng, Yiying
Li, Yan
Zhang, Hongwei
Zhang, Jingping
Liu, Qun
Primary target: A practical and effective copper-catalyzed amination strategy for synthesizing various benzylic amines from benzylic hydrocarbons is described (see scheme; DCE=1,2-dichloroethane). Xylene substrates can undergo diamination reactions using this method. The remarkable preference for primary over secondary benzylic C-H bonds has been observed for the first time. Copyright
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Doi:10.1134/S1070428012010101
(2012)Doi:10.1002/chem.201102583
(2011)Doi:10.1039/c2cc17393j
(2012)Doi:10.1055/s-0033-1339282
(2013)Doi:10.1002/chem.201101832
(2011)Doi:10.1016/j.ica.2011.10.015
(2012)
