General, Mild, and Metal-Free Synthesis of Phenyl Selenoesters from Anhydrides and Their Use in Peptide Synthesis

DOI: 10.1021/acs.joc.7b00173

Source and publish data:

Journal of Organic Chemistry p. 4588 - 4603 (2017)

Update date:2022-07-30

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Authors:

Temperini, Andrea

Piazzolla, Francesca

Minuti, Lucio

Curini, Massimo

Siciliano, Carlo

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Article abstract of DOI:10.1021/acs.joc.7b00173

A mild, practical, and simple procedure for phenyl selenoesters synthesis from several anhydrides and diphenyl diselenide was developed. This transition-metal-free method provides a straightforward entry to storable Fmoc-amino acid selenoesters which are effective chemoselective acylating reagents. An application to oligopeptide synthesis was illustrated.

Full text of DOI:10.1021/acs.joc.7b00173

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