Versatile Synthesis of Tropones by Reaction of Rhodium(II)-Stabilized Vinylcarbenoids with 1-Methoxy-1-buta-1,3-diene

DOI: 10.1021/jo00022a041

Source and publish data:

Journal of Organic Chemistry p. 6440 - 6447 (1991)

Update date:2022-08-04

Topics:

Authors:

Davies, Huw M. L.

Clark, T. Jeffrey

Kimmer, Garland F.

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Article abstract of DOI:10.1021/jo00022a041

Rhodium(II)-catalyzed decomposition of vinyldiazomethanes in the presence of 1-methoxy-1-<(trimethylsilyl)oxy>buta-1,3-diene leads to <3 + 4> annulation products by a tandem cyclopropanation/Cope rearrangement sequence.The resulting cycloheptadienes are r

Full text of DOI:10.1021/jo00022a041

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