Synthesis and properties of some Rh(I) catalytic complexes with dinitrogen ligands derived from 5-pyrido-1,4-benzodiazepin-4-ones

Article abstract of DOI:10.1016/S0040-4020(01)87141-6

A series of bidentate nitrogen ligands (3-8), and their [Rh (I) (NBD) (N-N)] ClO₄ complexes 11-14 (NBD-norbornadiene, N-N-dinitrogen ligand) were prepared. Conformational properties and stability of 4 and its catalytic complex 12 were reported.