Tetrahedron Letters p. 3973 - 3976 (1991)
Update date:2022-07-30
Topics:
Rossiter, Bryant E.
Eguchi, Masakatsu
Hernandez, Amelia E.
Vickers, Denise
Medich, John
et al.
Chiral amidocuprates, formed from CuI, n-butyl or methyl lithium and (S)-N-methyl-1-phenyl-2-(1-piperidinyl)ethanamine, (S)-MAPP, react enantioselectively with 5, 6, 7 and 8-membered cyclic enones to give products with up to 97percent e.e.The synthesis of (S)-MAPP is also reported.
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