Tetrahedron Letters p. 3887 - 3890 (1991)
Update date:2022-07-30
Topics:
Boyd, Derek R.
Sharma, Narain D.
Stevenson, Paul J.
Chima, Jagdeep
Gray, David J.
Dalton, Howard
Benzylic monooxygenation of benzocycloalkenes, 2-4, by enzymes in intact cultures of Pseudomonas putida UV4 yielded exclusively the [R] enantiomers, 6-8, and the derived ketones 10-12; by contrast, biotransformation of benzocyclobutene, 1, yielded both monooxygenation (5 and 9), dioxygenation (13,14 and 15), and trioxygenation (16) products.
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