Palladium-catalyzed asymmetric allylic alkylation using dimethyl malonate and its derivatives as nucleophile

DOI: 10.1016/S0957-4166(00)86120-0

Source and publish data:

Tetrahedron Asymmetry p. 663 - 666 (1991)

Update date:2022-07-30

Topics:

Authors:

Yamaguchi

Shima Shima

Yamagishi

Hida Hida

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Article abstract of DOI:10.1016/S0957-4166(00)86120-0

Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with sodium salt of dimethyl malonate and its derivatives has been successfully carried out in the presence of optically active diphosphine, such as (S)-BINAP. High enant

Full text of DOI:10.1016/S0957-4166(00)86120-0

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Product name:2-Benzyl-2-((E)-1,3-diphenyl-allyl)-malonic acid dimethyl ester

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