Facile Synthesis of γ,δ-Unsaturated β-Azido Carbonyl Compounds via Successive Nucleophilic Additions on Cinnamaldehyde Dimethyl Acetal Catalyzed by Trityl Hexachloroantimonate

DOI: 10.1246/cl.1988.1495

Source and publish data:

Chemistry Letters p. 1495 - 1496 (1988)

Update date:2022-07-30

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Authors:

Mukaiyama, Teruaki

Leon, Patrick

Kobayashi, Shu

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Article abstract of DOI:10.1246/cl.1988.1495

In the presence of a catalytic amount of trityl hexachloroantimonate, cinnamaldehyde dimethyl acetal successively reacts with silyl enol ethers or ketene silyl acetals and azidotrimethylsilane, to afford the corresponding γ,δ-unsaturated β-azido carbonyl

Full text of DOI:10.1246/cl.1988.1495

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