Journal of the Chemical Society. Perkin transactions I p. 2275 - 2276 (1991)
Update date:2022-09-26
Topics:
Marumo, Kiyotaka
Inoue, Sumie
Sato, Yoshiro
Kato, Hideo
The silylmethyl groups of (dialkylaminomethyl)trimethylsilanes 1 undergo ready lithiation with butyllithium and the resulting mixtures when quenched with chlorotrimethylsilane or aldehydes afford N,N-dialkyl(2,2,4,4-tetramethyl-2,4-disilapentyl)amines 3 or (dialkylaminomethyl)(2-hydroxyalkyl)dimethylsilanes 4.
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