Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1629 - 1636 (1991)
Update date:2022-07-29
Topics:
Troyanskii, E. I.
Strelenko, Yu. A.
Demchuk, D. V.
Samoshin, V. V.
Lutsenko, A. I.
Nikishin, G. I.
The homolytic heterocyclization of dialkyl-, and diaryl-acetylenes with 1,2-ethanedithiol leads stereoselectively to cis-2,3-disubstituted 1,4-dithianes.The stereochemistry of the reactions is determined by a combination of homolytic trans addition at the triple bond and intramolecular homolytic cis addition at the double bond.The main product of the heterocyclization of dimethyl acetylenedicarboxylate is dimethyl 5,6-dihydro-1,4-dithiin-2,3-dicarboxylate.
View MoreLinyi Shengxin Pharmaceutical R&D Co., Ltd
Contact:+86-18653953873
Address:West First of Yufeng Road, Yishui County
Contact:+86-25-85281586
Address:13F,Bld2#,South of Longpan Road
Jiangxi Dongxu Chemical Science & Technology Co.,Ltd
Contact:+86-791-86899381
Address:Nanchang, Jiangxi, China
Hangzhou Haiqiang Chemical Co.,Ltd.
Contact:+86-571-86960370
Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Wuhan Benjamin Pharmaceutical Chemical Co.,Ltd
Contact:86-27-52341789
Address:Room 1518 B suite, optical valley time square, No 111 Guanshan Road, Hongshan District,Wuhan,Hubei Province,China.
Doi:10.1016/j.ejmech.2016.02.062
(2016)Doi:10.1016/S0040-4020(02)00945-6
(2002)Doi:10.1039/c2ob25235j
(2012)Doi:10.1016/j.bmcl.2012.03.072
(2012)Doi:10.1134/S1070428015120313
(2015)Doi:10.1021/jm300317k
(2012)
