Angewandte Chemie - International Edition p. 1366 - 1369 (2012)
Update date:2022-08-04
Topics:
Shaikh, Yacoob
Albahily, Khalid
Sutcliffe, Matthew
Fomitcheva, Valeria
Gambarotta, Sandro
Korobkov, Ilia
Duchateau, Robbert
Small change, big difference: The introduction of an additional CH 2 group into the bridge of ligands with two P/N units leads to a different selectivity of the corresponding chromium-based catalysts. Whereas 1 produces an ethylene trimerization system, 2 provides an unprecedented ethylene tetramerization system that produces 1-octene with high purity and little or no polymer side products (see scheme; DMAO=Me3Al-depleted methylaluminoxane). Copyright
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(2012)
