Transition-state stabilization via dynamic molecular recognition: A concerted acid-base bifunctional catalysis in ester hydrolysis

DOI: 10.1016/S0040-4039(00)92300-1

Source and publish data:

Tetrahedron Letters p. 4757 - 4760 (1991)

Update date:2022-07-30

Topics: Ester Hydrolysis

Authors:

Motomura, Tadahiro

Inoue, Kazuhisa

Kobayashi, Kenji

Aoyama, Yasuhiro

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Article abstract of DOI:10.1016/S0040-4039(00)92300-1

An imidazole derivative 1a having a bisresorcinol moiety catalyzes the hydrolysis of p-nitrophenyl acetate in H₂O-CH₃CN (9:1) by the mechanism involving a concerted acid-base cooperation; nucleophilic attack of the imidazolyl group o

Full text of DOI:10.1016/S0040-4039(00)92300-1

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