Asymmetric Michael Addition of the N-Alkylidene Derivative of an α-Amino Ester to Methyl (E)-3-imidazol-3-yl>propenoate

DOI: 10.1246/bcsj.64.2739

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2739 - 2743 (1991)

Update date:2022-07-30

Topics:

Authors:

Yamamoto, Hidetoshi

Kanemasa, Shuji

Wada, Eiji

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Article abstract of DOI:10.1246/bcsj.64.2739

The exclusively diastereoselective asymmetric Michael addition of the lithiated methyl N-(2,2-dimethylpropylidene)glycinate to methyl (E)-3-<3R,7aS)-2-phenylperhydropyrrolo<1,2-c>imidazol-3-yl>propenoate is described.The synperiplanar conformer of the acc

Full text of DOI:10.1246/bcsj.64.2739

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