Verbindungen des Germaniums und Zinns. IX. Ein Stannacyclobuten aus einem sterisch ueberladenen Chlor(mesityl)stannan

DOI: 10.1016/0022-328X(91)80134-6

Source and publish data:

Journal of Organometallic Chemistry p. 343 - 348 (1991)

Update date:2022-09-26

Topics:

Authors:

Weidenbruch, Manfred

Schaefers, Karen

Schlaefke, Josephin

Peters, Karl

Schnering, Hans Georg von

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(91)80134-6

Reaction of trichloro(mesityl)stannane with 2,4,6-tri-t-butylphenyllithium (ArLi) in a 1/2 molar ratio, by rearrangement of one aryl group leads to chloro(mesityl)-2,4,6-tri-t-butylphenyl-<2-methyl-2(3,5-di-t-butylphenyl)propyl>stannane (3).Treatment of 3 with t-butyllithium gives the sterically congested stannacyclobutene derivative 4 which is fully characterized including an X-ray structure analysis.

Full text of DOI:10.1016/0022-328X(91)80134-6

Products guided by the article

Product name:(CH₃)2C₆H₂(CH₂)Sn(C₆H₂(C₄H₉)3)(C₆H₃(C₄H₉)2C(CH₃)2CH₂)

Cas No:137715-74-3

R&D Labs maybe for 137715-74-3

TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China
Sino-Biochemical Laboratory Co.,Ltd

Contact:+86 130 4215 5638

Address:Building 33 ,No.123 Shenmei Road , Pudong New District, Shanghai 201318, China
Twin International Co., Limited

Contact:+86-21-80309280

Address:No.345 Jinxiang Road, Jinqiao Export Processing Zone

Relevant to this article

A universal nucleoside with strong two-band switchable fluorescence and sensitivity to the environment for investigating DNA interactions

Doi:10.1021/ja3030388
(2012)
Circular dichroism and circularly polarized luminescence triggered by self-assembly of tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety

Doi:10.1039/c2cc31512b
(2012)
Mechanistic insight into the regioselective palladation of indole derivatives: Tetranuclear indolyl palladacycles with high C2-Pd or C3-Pd bond selectivity

Doi:10.1021/om300284t
(2012)
Synthesis of 1-aminoisoquinolines via the coinage metal cocatalyzed reaction of 2-alkynylbenzaldoximes with isocyanoacetates

Doi:10.1055/s-0034-1378654
(2014)
A comparative Study of the Decomposition of o-Alkynyl-Substituted Aryl Diazo Ketones. Synthesis of Polysubstituted β-Naphthols via Arylketene Intermediates

Doi:10.1021/jo00075a045
(1993)
IMMOBILIZED PENICILLINACYLASE: APPLICATION TO THE SYNTHESIS OF THE DIPEPTIDE ASPARTAME

Doi:10.1016/S0040-4039(00)84751-6
(1986)

Article Doi