Enantioselective total syntheses of bengamides B and E

DOI: 10.1016/S0040-4039(00)79423-8

Source and publish data:

Tetrahedron Letters p. 5907 - 5910 (1991)

Update date:2022-08-05

Topics:

Authors:

Broka Broka

Ehrler Ehrler

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79423-8

Convergent total syntheses of two sponge-derived cyclolysine derivatives - bengamides B (1) and E (2) - have been accomplished. The polyhydroxylated side chain common to both natural products was obtained from L-glucose and the hydroxylated caprolactam moiety of 1 was prepared using Evans' oxazolidinone chemistry. In the course of this work a new Horner-Emmons reagent incorporating one of Evans' chiral auxiliaries was developed.

Full text of DOI:10.1016/S0040-4039(00)79423-8

Products guided by the article

Product name:(E)-(2R,3S,4S,5R)-3,4,5-Tris-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-8-methyl-non-6-enoic acid ((S)-2-oxo-azepan-3-yl)-amide

Cas No:137789-59-4

R&D Labs maybe for 137789-59-4

Wuhan Better Organic Technology Inc.

Contact:13307163183

Address:Wuhan Economic&Technology Development Zone, Hubei
JIEJIE GROUP CO.,LTD.

Contact:+86 021-51698675

Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist

Relevant to this article

Synthesis, characterization and molecular structure of ruthenium complexes containing imidazole-2-carboxylic acid derivatives

Doi:10.1016/j.poly.2012.04.020
(2012)
Synthetic, structural, and physical investigations of the large linear and branched oligogermanes Ph₃GeGePh₂GePh₂GePh ₂H, Ge₅Ph₁₂, and (Ph₃Ge) ₄Ge

Doi:10.1021/om300385n
(2012)
Ruthenium-catalyzed highly regioselective cyclization of ketoximes with alkynes by C-H bond activation: A practical route to synthesize substituted isoquinolines

Doi:10.1021/ol301091z
(2012)
Structure-activity relationship of palladium phosphanesulfonates: Toward highly active palladium-based polymerization catalysts

Doi:10.1002/chem.201103694
(2012)
Efficient procedures to prepare primary and secondary alkyl halides from alkanols via the corresponding sulfonates under mild conditions

Doi:10.1002/adsc.201100736
(2012)
Rhodium/copper-catalyzed annulation of benzimides with internal alkynes: Indenone synthesis through sequential C-H and C-N cleavage

Doi:10.1002/anie.201200271
(2012)

Article Doi