Hydrosilylation of Enones: Platinum Divinyltetramethyldisiloxane Complex in the Preparation of Triisopropylsilyl and Triphenylsilyl Enol Ethers

DOI: 10.1021/jo00088a006

Source and publish data:

Journal of Organic Chemistry p. 2287 - 2288 (1994)

Update date:2022-08-04

Topics:

Authors:

Johnson, Carl R.

Raheja, Raj K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00088a006

Enones are regioselectively converted to triisopropylsilyl and triphenylsilyl enol ethers in high yields using triisopropylsilane or triphenylsilane and platinum divinyltetramethyldisiloxane complex 1 (Karstedt's catalyst).

Full text of DOI:10.1021/jo00088a006

Products guided by the article

Product name:Silane, [(4,4-dimethyl-1-cyclohexen-1-yl)oxy]tris(1-methylethyl)-

Cas No:137963-62-3

R&D Labs maybe for 137963-62-3

henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Hubei Xiangxi Chemical Industry Co.,Ltd

Contact:+86-710-3454830

Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
Chengdu Pukang Biotechnology Co., Ltd

Contact:+86-28-82550498

Address:No. 558 Rulin Road,Xinjin county,Chengdu city, China
Shanghai Demand Chemical Co., ltd，China

Contact:86-021-55237578/55239122

Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China

Relevant to this article

Regioselective and stereospecific cross-coupling of primary allylic amines with boronic acids and boronates through palladium-catalyzed C-N bond cleavage

Doi:10.1002/anie.201109171
(2012)
Additive controlled, stereoselective benzylation of 2- thioxotetrahydropyrimidin-4(1H)-ones via chiral induction from a remote stereocenter

Doi:10.1016/j.tetasy.2012.04.002
(2012)
Dipalladium(I) complexes of ortho- and para-functionalized 1,3-bis(aryl)triazenide ligands: Synthesis, structure and catalytic activity

Doi:10.1016/j.ica.2019.03.004
(2019)
A highly regioselective Friedl?nder reaction mediated by lanthanum chloride

Doi:10.1016/j.tetlet.2012.04.038
(2012)
A mild and green chemistry approach for the synthesis of symmetrical spirooxindole derivatives

Doi:10.1007/s13738-012-0187-z
(2013)
Rhodium-Catalyzed Denitrogenative Diazole-Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands

Doi:10.1021/acs.orglett.1c01092
(2021)

Article Doi