A meso-spiro[cyclopentadiene-isoporphyrin] from a phenylethynyl porphyrin platinum(II) pincer complex

DOI: 10.1002/anie.201109091

Source and publish data:

Angewandte Chemie - International Edition p. 3174 - 3177 (2012)

Update date:2022-07-31

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Authors:

Anabuki, Shoma

Shinokubo, Hiroshi

Aratani, Naoki

Osuka, Atsuhiro

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Article abstract of DOI:10.1002/anie.201109091

A good catch: The oxidation of a phenylethynyl Pt^II pincer complex with iodine led to formal reductive elimination but without the liberation of Pt^II, which was caught by the 2-pyridyl substituents on the Ni^II porphyrin. The unique reactivity of the Pt^II pincer complex led to the formation of a meso-spiro[cyclopentadiene- isoporphyrin]. Copyright

Full text of DOI:10.1002/anie.201109091

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