A NEW ROUTE TO γ-SUBSTITUTED γ-LACTONES AND δ-SUBSTITUTED δ-LACTONES BASED ON THE REGIOSELECTIVE β-SCISSION OF ALKOXY RADICALS GENERATED FROM TRANSANNULAR HEMIACETALS

DOI: 10.1016/S0040-4020(01)89727-1

Source and publish data:

Tetrahedron p. 7245 - 7258 (1991)

Update date:2022-07-30

Topics:

Authors:

Kobayashi, Kazuhiro

Sasaki, Akiyoshi

Kanno, Yoshikazu

Suginome, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)89727-1

A new general synthesis of γ-substituted γ-lactones and δ-substituted δ-lactones including dihydro-5-octyl-2(3H)-furanone, a natural pheromone, is described.The synthesis involves the regioselective β-scission of alkoxy radicals generated from transannular hemiacetals as the key step. Key Words: γ-Lactones; δ-Lactones; Mercury(II) Oxide-Iodine Reagent; Photolysis; β-Scission of Alkoxyl Radicals

Full text of DOI:10.1016/S0040-4020(01)89727-1

Products guided by the article

Product name:2(3H)-Furanone, dihydro-5-(3-iodopropyl)-5-phenyl-

Cas No:138145-91-2

R&D Labs maybe for 138145-91-2

Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
TAIXING BEST NEW MATERIALS CO., LTD

Contact:0523-87998158;

Address:No.18 Zhonggang Road，Taixing City ，Jiangsu , China
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai

Relevant to this article

Stereoselective Synthesis and Antiallodynic Activity of 3-Hydroxylated Paroxetines

Doi:10.1002/cmdc.202000674
(2021)
Metabolic activation of the genotoxic environmental contaminants 2- and 3-nitrofluoranthene in variants of Salmonella typhimurium TA98

Doi:10.1093/mutage/10.6.497
(1995)
Efficient approach to 1,2-diazepines via formal diazomethylene insertion into the C-C bond of cyclobutenones

Doi:10.1021/ol301474g
(2012)
Synthesis of novel Schiff base analogues of 4-amino-1,5-dimethyl-2- phenylpyrazol-3-one and their evaluation for antioxidant and anti-inflammatory activity

Doi:10.1016/j.bmc.2012.04.058
(2012)
Synthesis, characterization and DFT study of 4H-benzo[h]chromene derivatives

Doi:10.1016/j.molstruc.2012.03.018
(2012)
Investigation of reactions postulated to occur during inhibition of ribonucleotide reductases by 2′-azido-2′-deoxynucleotides

Doi:10.1016/j.tet.2012.04.050
(2012)

Article Doi