HYDROZIRCONATION / TRANSMETALATION / ALKYLATION: DIRECT ONE-POT CONVERSION OF 1-ALKYNES TO E-1,2-DISUBSTITUTED ALKENES

DOI: 10.1016/S0040-4039(00)93519-6

Source and publish data:

Tetrahedron Letters p. 5647 - 5650 (1991)

Update date:2022-08-05

Topics:

Authors:

Lipshutz, Bruce H.

Kato, Kaneyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)93519-6

Hydrozirconation of terminal acetylenes followed by transmetalation of the intermediate vinyl zirconate with a higher order cyanocuprate affords mixed vinylic cuprates which undergo alkylations with a variety of electrophiles.

Full text of DOI:10.1016/S0040-4039(00)93519-6

Products guided by the article

Product name:4-Undecen-2-ol, 1-(phenylmethoxy)-, (E)-

Cas No:138175-89-0

R&D Labs maybe for 138175-89-0

Jitat Company Ltd

Contact:852-27701081

Address:Room 2509, New Tech Plaza, 34 Tai Yau St., San Po Kong, HK
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA
hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549
Zhejiang Tianyu Pharmaceutical Co., Ltd.

Contact:+86-576-84177669, 89189665,89189688,84168770

Address:Jiangkou Development Zone, Huangyan, Taizhou City, Zhejiang

Relevant to this article

Chemoenzymatic synthesis of GDP-L-fucose derivatives as potent and selective α-1,3-fucosyltransferase inhibitors

Doi:10.1002/adsc.201100940
(2012)
Pronounced effect of substituents on the intramolecular electron-transfer rates in mixed-valence biferrocenium triiodide complexes

Doi:10.1021/om00038a012
(1992)
Chiral phosphoric acid catalyzed enantioselective transfer deuteration of ketimines by use of benzothiazoline as a deuterium donor: Synthesis of optically active deuterated amines

Doi:10.1021/ol3012869
(2012)
Design of co-crystals/salts of aminopyrimidines and carboxylic acids through recurrently occurring synthons

Doi:10.1021/cg3005954
(2012)
Preparation of tertiary amides via aryl, heteroaryl, and benzyl organozinc reagents; Scope and limitations

Doi:10.1016/j.tetlet.2012.04.114
(2012)
Gold and Palladium Mediated Bimetallic Catalysis: Mechanistic Investigation through the Isolation of the Organogold(I) Intermediates

Doi:10.1021/acscatal.9b02275
(2019)

Article Doi