HYDROZIRCONATION / TRANSMETALATION / ALKYLATION: DIRECT ONE-POT CONVERSION OF 1-ALKYNES TO E-1,2-DISUBSTITUTED ALKENES

DOI: 10.1016/S0040-4039(00)93519-6

Source and publish data:

Tetrahedron Letters p. 5647 - 5650 (1991)

Update date:2022-08-05

Topics:

Authors:

Lipshutz, Bruce H.

Kato, Kaneyoshi

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Article abstract of DOI:10.1016/S0040-4039(00)93519-6

Hydrozirconation of terminal acetylenes followed by transmetalation of the intermediate vinyl zirconate with a higher order cyanocuprate affords mixed vinylic cuprates which undergo alkylations with a variety of electrophiles.

Full text of DOI:10.1016/S0040-4039(00)93519-6

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