ZINC(II)-CHLORIDE INDUCED THIOALKYLATION OF ALUMINIUM ENOLATES; ENANTIOSELECTIVE SYNTHESIS OF ESTRADIOL-3-METHYL-17-tert-BUTYL DIETHER

DOI: 10.1016/S0040-4020(01)88282-X

Source and publish data:

Tetrahedron p. 7583 - 7592 (1991)

Update date:2022-08-03

Topics:

Authors:

Groth, Ulrich

Koehler, Thomas

Taapken, Thomas

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Article abstract of DOI:10.1016/S0040-4020(01)88282-X

Zinc(II)-chloride induced thioalkylation of the aluminium enolate 6 generated by conjugate reduction of the enone 5 leads - directly or via its trimethylsilylenol ether 6 - to alkylated hydrindanones 10 which are important intermediates in the synthesis o

Full text of DOI:10.1016/S0040-4020(01)88282-X

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