Very high stereoselectivity in organocatalyzed desymmetrizing aldol reactions of 3-substituted cyclobutanones

DOI: 10.1039/c2ob25813g

Source and publish data:

Organic and Biomolecular Chemistry p. 5045 - 5048 (2012)

Update date:2022-08-05

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Authors:

Aitken, David J.

Bernard, Angela M.

Capitta, Francesca

Frongia, Angelo

Guillot, Regis

Ollivier, Jean

Piras, Pier Paolo

Secci, Francesco

Spiga, Marco

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Article abstract of DOI:10.1039/c2ob25813g

N-Phenylsulfonyl (S)-proline catalyzes the direct aldol reaction of 3-substituted cyclobutanones and aryl aldehydes in good yield and with excellent diastereoselectivity and enantioselectivity. This desymmetrization process provides highly functionalized

Full text of DOI:10.1039/c2ob25813g

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