Utilization of Me3SiSnBu3 in organic synthesis I. Generation of stannyl anion from Me3SiSnBu3 and R4NX

DOI: 10.1016/0022-328X(93)80407-3

Source and publish data:

Journal of Organometallic Chemistry p. 255 - 260 (1993)

Update date:2022-08-03

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Authors:

Mori, Miwako

Kaneta, Naotake

Isono, Naohiro

Shibasaki, Masakatsu

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Article abstract of DOI:10.1016/0022-328X(93)80407-3

A metal free stannyl anion generated from Me3SiSBu3 and R4NX in DMF reacted with an aryl halide bearing carbonyl group to produce an aryl anion via the so-called halogen-metal exchange process, which reacted with a carbonyl group to afford a cyclized product in good yield.

Full text of DOI:10.1016/0022-328X(93)80407-3

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