Journal of Organic Chemistry p. 6358 - 6364 (2012)
Update date:2022-08-03
Topics:
Billard, Francois
Robiette, Raphael
Pospisil, Jiri
A new modification of Julia-Kocienski olefination reaction based on the use of cation-specific chelating agents that yields 1,3-dienes with predictable (E/Z)-selectivity on newly created double bond was developed. The influence of the aldehyde structure on reaction (E/Z) selectivity is discussed and rationalized.
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