BENZILIC ACID REARRANGEMENTS IN THE REACTIONS OF ARYL VICINAL TRICARBONYL DERIVATIVES WITH ALDEHYDE SCHIFF BASES

DOI: 10.1016/S0040-4039(00)79459-7

Source and publish data:

Tetrahedron Letters p. 6039 - 6042 (1991)

Update date:2022-08-04

Topics:

Authors:

Wasserman, Harry H.

Ennis, David S.

Vu, Chi B.

Schulte, Gayle K.

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Article abstract of DOI:10.1016/S0040-4039(00)79459-7

Reactions of aryl and hetero vicinal tricarbonyl derivatives with aldehyde Schiff bases of the general structure RCH2CHO lead to pyrrolinone derivatives by benzilic acid-related rearrangements, driven, most probably, by iminium ion intermediates.

Full text of DOI:10.1016/S0040-4039(00)79459-7

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