
Journal of the Chemical Society. Chemical communications p. 1248 - 1250 (1981)
Update date:2022-08-05
Topics:
Cass, Quezia B.
Jaxa-Chamiec, Albert A.
Sammes, Peter G.
The direct condensation of saturated or unsaturated aldehydes with methyl phenylsulphinylacetate can be effected with the products undergoing base-catalysed rearrangements, those from saturated aldehydes yielding γ-hydroxy-αβ-unsaturated esters, whilst crotonaldehyde gives rise to methyl 6-phenylsulphinylhexa-2,4-dienoate.
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