Evidence for the importance of π-π attractive interactions in enantioselective Diels-Alder reactions chiral catalysts of type (RO)2TiCl2

DOI: 10.1016/0040-4039(91)80149-Z

Source and publish data:

Tetrahedron Letters p. 6289 - 6292 (1991)

Update date:2022-08-02

Topics:

Authors:

Corey Corey

Matsumura

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80149-Z

Reaction of diol 4 with Ti(O i-Pr)₄ followed by SiCl₄ results in formation of the Ti (IV) complex 5 which is an exceptionally effective catalyst for enantioselective Diels-Alder reactions. The origin of the high enantioselectivities

Full text of DOI:10.1016/0040-4039(91)80149-Z

Products guided by the article

Product name:3-((1S,2R,4R,7S)-7-Benzyloxymethyl-bicyclo[2.2.1]hept-5-ene-2-carbonyl)-oxazolidin-2-one

Cas No:138809-53-7

R&D Labs maybe for 138809-53-7

Suzhou Kangrun Pharmaceutical, Inc

Contact:86-512-63912376，63913329

Address:Building 2, No. 2358 ,Chang'an Rd, Wujiang Economic Development Zone Pioneering park, china
Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
Hunan Dinuo Pharmaceutical Co.,Ltd.

Contact:86-731-88280100*8561

Address:Bio-pharmaceutical industrial park, Liuyang, Hunan, China
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Sino-Japan Chemical Co., Ltd.

website:http://www.sjc.com.tw

Contact:(886) 2-2396-6223

Address:14Fl., No. 99. Sec. 2, Jen Ai Road

Relevant to this article

First total synthesis of a naturally occurring nucleoside disulfide: 9-(5′-Deoxy-5′-thio-β-d-xylofuranosyl)adenine disulfide

Doi:10.1016/j.cclet.2012.06.011
(2012)
Optically Active Phosphines. Facile Preparation of the Optically Active n-Propylmethylbenzyl- and Methylphenylbenzylphosphine Oxides as Precursors to the Corresponding Tertiary Phosphines

Doi:10.1021/ja00352a035
(1983)
Fabrication of well-defined crystalline azacalixarene nanosheets assisted by Se...N non-covalent interactions

Doi:10.1039/c2cc33760f
(2012)
One-Pot, Three-Step Synthesis of Benzoxazinones via Use of the Bpin Group as a Masked Nucleophile

Doi:10.1021/acs.orglett.1c00623
(2021)
Mechanistic pathways in phosphate ester photochemistry

Doi:10.1016/0040-4039(91)85027-3
(1991)
Synthese, activite antiparasitaire et antifongique de thioureines a motif aminoacide

Doi:10.1016/0223-5234(91)90122-4
(1991)

Article Doi